I love Shokuhou Misaki!

The main draw for the character (for me) is not the sexuality. It's her character and character flaws. Being teased by a headass Touma that saves her (the original tsundere and innocent girl) and once she's saved by him again in NT11 she regains hope.

Well. This isn't to say that her sexuality plays no part in her character being complex. In NT11 and Astral Buddy she gets mocked for her flat chest by Touma and a Tokiwadai head. Touma particularly mocks her for not being a mature woman. So that's a role she tries to fulfill.

On that girl's flaws. How Misaki judges Kuroko and Mikoto's relationship as Kuroko not needing Mikoto but she herself is fairly attached to a boy that can't remember her. Which is displayed in NTR22 when THAT Touma manipulates her and leads to her weakest moment.

She's still caring of that boy like when she ran away with his right arm in NT22 so he wouldn't put himself in danger anymore.

I like how psychological Shokuhou is with people, but she has a soft spot for Touma. The day she compromises on these hypocrisies will be spectacular.